Try using the code below for a solution:
<div class="col text-center" ng-repeat="event in weekDay.events">
<div ng-show="$index%2==0">
<small>{{ event.times }}</small>
<small>{{ weekDay.events[$index+1].times }}</small>
</div>
</div>
Below is a small example to demonstrate how it works:
!DOCTYPE html>
<html>
<head>
<title></title>
<meta charset="utf-8" />
</head>
<body ng-app="app" ng-controller="ctrl">
<div ng-repeat="event in weekDay.events" style="border:1px solid black">
<div ng-show="$index%2==0">
{{event.times}}
{{weekDay.events[$index+1].times}}
</div>
</div>
<script src="../lib/angular.js"></script>
<script>
var app = angular.module('app', []);
app.controller('ctrl', function ($scope) {
$scope.weekDay = {
"events": [
{ "times": "one", "day": "1" },
{ "times": "two", "day": "2" },
{ "times": "three", "day": "3" },
{ "times": "four", "day": "4" },
{ "times": "five", "day": "5" },
{ "times": "six", "day": "6" },
{ "times": "seven", "day": "7" },
{ "times": "eight", "day": "8" },
]
};
});
</script>